IV. Stoichiometry and Solution questions

Stoichiometry practice problems

Stoichiometry practice problems

There are a total of 48 stoichiometry practice problems, which are important content-oriented in the summary part of this chapter. Click the ‘Answer’ button to see the corresponding answers and explanations, and click the ‘Go back’ button to slove the next questions.

1. What is the density when 32g of an unknown compound is contained in the 2cm edge of a cube?

A. 32 g/cm3

B. 16 g/cm3

C. 8 g cm3

D. 4 g/cm3

E. 2 g/cm3

2. Which of the following has the highest density at STP?

A. H2 in 2L container

B. F2 in 20L container

C. Cl2 in 40L container

D. Br2 in 40L container

E. I2 in 160L container

3. What is the mass percent of carbon in C3H6O3?

A. 15%

B. 20%

C. 40%

D. 50%

E. 60%

4. What is the mass percent of hydrogen in water?

A. 11.1%

B. 88.9%

C. 12.5%

D. 25.0%

E. 9.0%

5. What is the mass percentage of oxygen in Cu(NO3)2, approximately?

A. 9 %

B. 26 %

C. 43 %

D. 51 %

E. 65 %

6. 40 g of Cl is found in 110 g of AgCl compound. What is the mass percentage of Ag in the compound?

A. 36.4%

B. 63.6%

C. 107.9%

D. 98.1%

E. 67.8%

7. 50g of SO2 is to be dissolved in water. If the mass percentage of SO2 in the solution is 25%, then how many grams of water should be prepared?

A. 12.5g

B. 50.0g

C. 100.0g

D. 150.0g

E. 200.0g

8. How many moles of calcium and oxygen each are found in 50g of CaCO3?

A. 0.5mole of calcium, 1.5mole of oxygen

B. 0.5mole of calcium, 0.5mole of oxygen

C. 1.5mole of calcium, 1.5mole of oxygen

D. 1.2mole of calcium, 1.0mole of oxygen

E. 1.2mole of calcium, 3.6mole of oxygen

9. How many molecules of carbon are in 120g of saccharin, C7H5NO3S, approximately?

A. 2.8×1024

B. 4.0×1023

C. 6.0×1023

D. 2.0×1023

E. 1.2×1024

10. How many grams of glucose, C6H12O6, are equal to 2 moles of glucose?

A. 90g

B. 180g

C. 360g

D. 400g

E. 460g

11. If ZnCl2 contains 2.1×1024 atoms, what is the mass of zinc chloride?

A. 39 g

B. 135 g

C. 270 g

D. 473 g

E. 2.8 × 1026 g

12. If sodium oxide, Na2O, contains 12 × 1022 atoms, which of the following is an INCORRECT statement?

A. The mass of Na2O is 12.4 g.

B. The atoms of cation is 2.4×1023.

C. The total moles of ions is 0.2.

D. The mass of O is 3.2g.

E. The atomic numbers of sodium oxide is equal to anion.

13. Palladium, Pd, is one of the important metals for making PFM (porcelain fused metal) crowns in a dental laboratory. How many atoms are in 212g of Pd?

A. 3.0 × 1023

B. 6.0 × 1023

C. 1.2 × 1024

D. 6.4 × 1024

E. 1.2 × 1025

14. How many grams of nitrogen are in 16g of N2H4?

A. 14g

B. 28g

C. 42g

D. 56g

E. 64g

15. Unknown compound is composed of 224g of iron and 96g of oxygen. What is the empirical formula for the unknown compound?

A. FeO3

B. Fe2O6

C. Fe2O3

D. Fe4O6

E. Fe3O

16. Percent composition of an unknown compound is 43.4% Na, 11.3% C, and 45.3% O by mass. What is the empirical formula for the unknown molecule?

A. Na2CO3

B. Na4CO6

C. NaC2O3

D. Na8C2O12

E. Na2CO6

17. The empirical formula of Caproic acid is C3H6O. What is the molecular formula when the molecular weight of Caproic acid is 116 amu?

A. C1H2O0.5

B. C3H6O

C. C6H12O2

D. C9H18O3

E. C12H24O4

18. The molecular mass of an unknown compound is 58g/mol. Which of the following could be the empirical formula for the unknown compound?

A. C4H10

B. C2H5

C. C2H6

D. CH3

E. C2H3

19. Carbon is reacted with Fe2O3 to produce iron. What is the sum of the product coefficient when the following equation is balanced?

  Fe2O3 + C  →   Fe + CO2

A. 2

B. 3

C. 5

D. 7

E. 9

20. Butane is burned in air. What is the sum of the coefficient from the balanced equation for the reaction?

A. 4

B. 15

C. 18

D. 25

E. 33

21. 180g of C3H8O reacted with an excess of O2 produces 277.2g of CO2. What is the percent yield of CO2?

     2C3H8O + 9O2  →   6CO2 + 8H2O

A. 70%

B. 75%

C. 80%

D. 85%

E. 90%

22. If 67.2g of Fe reacts with 32.0g of O2, how many grams of Fe2O3 are produced from the following equation?

    4Fe + 3O2  →   2Fe2O3

A. 43g

B. 52g

C. 80g

D. 96g

E. 172g

23. How many grams of PH3 are used to produce 54g of H2O in the following reaction? (O2 is the excess reactant)

     4PH3 + 8 O2  →  P4O10 + 6H2O

A. 17g

B. 34g

C. 51g

D. 60g

E. 68g

24. How many grams of Cl2 are required to react with 280g of Si in the following reaction?

     Si + 2Cl2  →  SiCl4

A. 350g

B. 700g

C. 1400g

D. 2800g

E. 3500g

25. How many g of MgCl2 is dissolved in 9g of water when the mass percent of MgCl2 in the solution is 40%?

A. 3g

B. 6g

C. 9g

D. 12g

E. 15g

26. 400 mL of solution is created by dissolving 148 g of KCl in water. What is the molarity of the KCl solution?

A. 5 M

B. 10 M

C. 20 M

D. 185 M

E. 370 M

27. How many g of aspirin, C9H8O4, are prepared in 250mL of dichloromethane, CH2Cl2, to produce a 1.o M solution of aspirin?

A. 0.25 g

B. 25 g

C. 45 g

D. 90 g

E. 180 g

28. 300mL of 12M NaOH is dissolved in water to produce 4M NaOH solution. How much water is added?

A. 300 mL

B. 600 mL

C. 900 mL

D. 1200 mL

E. 1500 mL

29. What is the molar concentration of oxygen in a 0.25M H3PO4 solution?

A. 0.25 M

B. 0.5 M

C. 0.75 M

D. 1.0 M

E. 4.0 M

30. 18g of acetic acid, CH3COOH, is dissolved in 200g of water. What is the molality of the acetic acid solution?

A. 0.3 m

B. 1.5 m

C. 3.0 m

D. 4.5 m

E. 5.0 m

31. 400g of unknown compound is dissolved in 5kg of water. If the molality of the solution is 4m, which of the following is the unknown compound?

A. HF

B. NaOH

C. Ca(OH)2

D. H2SO4

E. HI

32. When 5.0M NaCl solution has a density of 1.09g/mL, what is the molality of this solution? (M.W. of NaCl = 58g/mol)

A. 3.50

B. 6.25

C. 10.40

D. 11.25

E. 15.50

33. What volume of o.85M KOH(aq) is needed to neutralize 60mL of 0.35 M HBr?

A. 145.7 mL

B. 72.8 mL

C. 49.4 mL

D. 24.7 mL

E. 12.4 mL

34. What is the molarity of a final solution of KOH when 30.0mL of water is added to 50.0mL of 12.5M KOH?

A. 7.8 M

B. 15.6 M

C. 20.8 M

D. 31.2 M

E. 41.6 M

35. What is the final concentration of BaCl2 when 80ml of 4M BaCl2 solution is diluted to 50ml of BaCl2 solution?

A. 1.3M

B. 2.5M

C. 5.0M

D. 6.4M

E. 12.8M

36. When 2.0M boric acid, H3BO3, neutralizes 750 mL of 5.0M sodium hydroxide, NaOH, what volume of boric acid is needed?

A. 312 mL

B. 625 mL

C. 938 mL

D. 1250 mL

E. 1875 mL

37. What molarity of Mg(OH)2 is required when 5 L of Mg(OH)2 neutralizes 100 L of 15M HCl?

A. 1 M

B. 75 M

C. 150 M

D. 300 M

E. 600 M

38. What is the product from the reactant?

   Pb(NO3)2(aq) + Na2SO4(aq)   →

A. PbNa2(aq) + (NO3)2SO4(aq)

B. PbSO4(s) + 2NaNO3(aq)

C. PbNa2(aq) + 2NaNO3(aq)

D. PbSO4(s) + (NO3)2SO4(aq)

E. Pb(NO2)2(aq) + Na2SO3(aq) + O2(g)

39. Which of the following is the redox reaction?

A. 2AgNO3(aq) + Cu(s)  →  Cu(NO3)2(aq) + 2Ag(s)

B. 3MgCl2(aq) + 2K3PO4(aq)  →  Mg3(PO4)2(s) + 6KCl(aq)

C. LiOH(aq) + HI(aq)  →  LiI(aq) + H2O(l)

D. AgNO3(aq) + NaCl(aq)  →  AgCl(s) + NaNO3

E. HF(aq) + KOH(aq)  →  H2O(l) + KF(aq)  

40. Which of the following is an insoluble compound?

A. AgCl

B. H2SO4

C. NaI

D. CaCl2

E. NaOH

41. Which of the following is NOT dissociated in water?

A. CH3COOH

B. KOH

C. C12H22O11

D. HNO3

E. KBr

42. Which of the following is the strong acid?

A. HF

B. Ba(OH)2

C. NH3

D. HBr

E. H3PO4

43. Which of the following is the reducing agent in the reaction below?

   ZnO(s) + C(s)  →   Zn(s) + CO(g)

A. ZnO

B. C

C. Zn

D. CO

E. O

44. Which of the following is correct for the following reaction?

   2KI + Cl2  →  2KCl + I2

A. Cl2 is the oxidizing agent.

B. KCl is the reducing agent.

C. Cl is oxidized.

D. I is reduced.

E. A and B

45. The oxidation number of P in HPO42- is __________.

A. -1

B. -2

C. 0

D. +5

E. +7

46. Which of the following compounds has the same oxidation number of S as in H2SO4?

A. S2O32-

B. MgSO4

C. CdS

D. SO32-

E. Na2S

47. What is the net ionic equation from the following reactants?

   BaCl2(aq) + Na2SO4(aq)  →

A. Ba2+(aq) + 2Cl(aq) + 2Na+(aq) + SO42-(aq) 

B. 2Cl(aq) + 2Na+(aq)  →  2NaCl(aq)

C. BaCl2(aq) + Na2SO4(aq)  →  BaSO4(s) + 2NaCl(aq)

D. Ba2+(aq) + SO42-(aq)  →  BaSO4(s)

E. Ba2+(aq) + 2Cl(aq) + 2Na+(aq) + SO42-(aq)  →  BaSO4(s) + 2Na+(aq) + 2Cl(aq)

48. How many moles of water and chloride ion are needed to c0mplete the balanced redox reaction from the unbalanced net ionic equation?

   Cr2O72- + Cl  →  Cr3+ + Cl2

A. 2 moles of water, 12 moles of chloride ion

B. 7 moles of water, 14 moles of chloride ion

C. 7 moles of water, 6 moles of chloride ion

D. 1 moles of water, 6 moles of chloride ion

E. 14 moles of water, 12 moles of chloride ion

Answers

10. C

Molecular mass of C6H12O6 = 12×6+1×12+16×6 = 180g/mol

Grams of C6H12O6 = 180g/mol × 2 mol = 360g

17. C

Molecular mass of C3H6O: 12×3+6+16 = 58g/mol

Unknown constant xx × 58g/mol = 116 g/mol

                      x = 2

Molecular formula: 2× C3H6O = C6H12O2

29. D

0.25M × 4 moles of oxygen = 1.0 M

38. B

Pb(NO3)2(aq) + Na2SO4(aq) 

Ion equation: Pb2+(aq) + 2NO3(aq) + 2Na+(aq) + SO42-(aq)

Products:  →  PbSO4(s) +2NaNO3(aq)

40. A

When a halide (Cl, Br, I) is bonded with Ag+, Hg2+, or Pb2+, it becomes an insoluble compound.

41. C

Alcohols (CH3OH, CH3CH2OH) and organic compounds (C12H22O11) are non-electrolytes in water.

42. D

Strong acids: HCl, HBr, HI, H2SO4, HNO3, HClO4

Weak acids: H3PO4, CH3COOH, HF, HCN

Strong bases: LiOH, NaOH, KOH, Mg(OH)2, Ca(OH)2, Sr(OH)2, KBr, NaCl, NaOH, ionic compounds

Weak bases: NH3, CH3NH2

45. D

HPO42- : O(-2), H(+1, bonded with a nonmetal)    

   (+1)×1 +P +(-2)×4 = -2

   P = +5

48. C

Completed balanced redox reaction:  Cr2O72- + 14H+ + 6Cl  →   2Cr3+ + 7H2O + 3Cl2

Processing

Equations

Net ionic equation

Separation into oxidation and reduction

Balance atoms except H, O

Balance O by adding H2O

Balance H by adding H+

Balance charges by adding electrons

Multiply by coefficient to cancel electrons

Cancel electrons and complete the balanced redox reaction